What a fantastic home for two little finches! Of course, you now have plenty of room to add more.

When I had a walk-in aviary for a while, I just turned the birds loose in there cold turkey. They had the same feeders they had always had (seed hoppers), just in different places, and it didn't take them any time to find them. Same with the waterers, I used the same tube waterers they were used to, and so the transition was pretty easy. As long as you leave their old cage in the doorway, they will probably continue to use it. I would take away the cage completely, and then watch to see how they do. The feeder is quite high, you might want to put it on the floor and then gradually move it up, but the birds find their way around pretty quickly. That's awesome that they went right for that nest!
And welcome to the forum! There's lots of good reading at the Finch Information Center, linked at left, and the members are always ready to answer questions. We have quite a few members from Georgia.